On the energy conversion efficiency of the bulk photovoltaic effect

The bulk photovoltaic effect (BPVE) leads to directed photo-currents and photo-voltages in bulk materials. Unlike photo-voltages in p-n junction solar cells that are limited by carrier recombination to values below the bandgap energy of the absorbing material, the BPVE photo-voltages have been shown to greatly exceed the bandgap energy. Therefore the BPVE is not subject to the Shockley-Queisser limit for sunlight to electricity conversion in single junction solar cells and experimental claims of efficiencies beyond this limit have been made. Here, we show that BPVE energy conversion efficiencies are, in practice, orders of magnitude below the Shockley-Queisser limit of single junction solar cells and are subject to different, more stringent limits. The name BPVE stands for two different fundamental effects, the shift current and the injection current. In both of these, the voltage bias necessary to produce electrical energy, accelerates both, intrinsic and photo-generated, carriers. We discuss how energy conservation alone fundamentally limits the BPVE to a bandgap-dependent value that exceeds the Shockley Queisser limit only for very small bandgaps. Yet, small bandgap materials have a large number of intrinsic carriers, leading to high conductivity which suppresses the photo-voltage. We discuss further how slightly more stringent fundamental limits for injection (ballistic) currents may be derived from the trade-off between high resistivity, needed for a high voltage, and long ballistic transport length, needed for a high current. We also explain how erroneous experimental and theoretical claims of high efficiency have arisen. Finally, we calculate the energy conversion efficiency for an example 2D material that has been suggested as candidate material for high efficiency BPVE based solar cells and show that the efficiency is very similar to the efficiency of known 3D materials.Comment: 23 pages, 6 figure

Solar-thermal and hybrid photovoltaic-thermal systems for renewable heating

Grantham Briefing Papers analyse climate change and environmental research linked to work at Imperial College London, setting it in the context of national and international policy and the future research agenda. This paper and other Grantham publications are available from: www.imperial.ac.uk/grantham/publicationsThis paper looks at the barriers and opportunities for the mass deployment of solar-thermal technologies and offers a vision for the future of solar-thermal systems. HEADLINES: -Heat constitutes about half of total global energy demand. Solar heat offers key advantages over other renewable sources for meeting this demand through distributed, integrated systems. -Solar heat is a mature sustainable energy technology capable of mass deployment. There is significant scope for increasing the installed solar heat capacity in Europe. -Only a few European countries are close to reaching the EU target of 1 m2 of solar-thermal installations per person. -One key challenge for the further development of the solar-thermal market arises from issues related to the intermittency of the solar resource, and the requirement for storage and/or backup systems. The former increases investment costs and limits adaptability. -An analysis of EU countries with good market development, suggests that obligation schemes are the best policy option for maximising installations. These do not present a direct cost to the public budget, and determine the growth of the local industry in the long term. -Solar-thermal collectors can be combined with photovoltaic (PV) modules to produce hybrid PV-thermal (PV-T) collectors. These can deliver both heat and electricity simultaneously from the same installed area and at a higher overall efficiency compared to individual solar-thermal and PV panels installed separately. --Hybrid PV-T technology provides a particularly promising solution when roof space is limited or when heat and electricity are required at the same time.Preprin

Performance Analysis and Fault Diagnosis Method for Concentrator Photovoltaic Modules

Concentrator Photovoltaic (CPV) systems use high efficiency multi-junction solar cells with efficiencies >40%, but the module efficiency is often much lower. The increased complexity of a CPV module, with optics, receiver and the tracker gives an increased probability that faults will arise during the operational lifetime. In addition, a location like India has varied atmospheric conditions that further complicates the diagnosis of faults. It is therefore important to decouple effects due to the external environment (such as the atmosphere) from effects due to the degradation of the module. By applying a computer model to outdoor CPV test data in Bangalore, India we have established a method to assess the performance of the CPV module and finally we present a method to diagnose faults in the module.Comment: 7 pages, 12 figure

Multi-dimensional modeling of solar cells with electromagnetic and carrier transport calculations

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Electronic and optical properties of SixGe1-x-ySny alloys lattice-matched to Ge

We present a combined experimental and theoretical analysis of the evolution of the near-band-gap electronic and optical properties of SixGe1-x-ySny alloys lattice-matched to Ge and GaAs substrates. We perform photoreflectance (PR) and photoluminescence (PL) measurements on SixGe1-x-ySny epitaxial layers grown via chemical vapor deposition for Si (Sn) compositions up to x=9.6% (y=2.5%). Our measurements indicate the presence of an indirect fundamental band gap, with PL observed Ë 200-250 meV lower in energy than the direct E0 transition identified by PR measurements. The measured PL is Ge-like, suggesting that the alloy conduction band (CB) edge is primarily derived from the Ge L-point CB minimum. Interpretation of the PR and PL measurements is supported by atomistic electronic structure calculations. Effective alloy band structures calculated via density functional theory confirm the presence of an indirect fundamental band gap, and reveal the origin of the observed inhomogeneous broadening of the measured optical spectra as being alloy-induced band hybridization occurring close in energy to the CB edge. To analyze the evolution of the band gap, semiempirical tight-binding (TB) calculations are employed to enable calculations for large supercell sizes. TB calculations reveal that the alloy CB edge is hybridized in nature, consisting at low Si and Sn compositions of an admixture of Ge L-, G-, and X-point CB edge states, and confirm that the alloy CB edge retains primarily Ge L-point CB edge character. Our experimental measurements and theoretical calculations confirm a direct transition energy close to 1 eV in magnitude for Si and Sn compositions x=6.8%-9.6% and y=1.6%-2.2%